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Atomic Engineering of Two-Dimensional Materials Using Electron Irradiation

Cong Su

Controlling the exact atomic structure is an ultimate form of materials engineering. Atomic manipulation and atom-by-atom assembly can create functional structures that are hard to synthesize chemically. Defects at the one- or few-atom-scale have intriguing properties that can be applied to fields like quantum engineering (e.g. nitrogen vacancy center, single photon emitter, etc. ), and single-atom catalysis.

Historically, scanning tunneling microscopy (STM) has demonstrated good stepwise control of single atoms, leading to physicochemical insights and technological advances. However, their scalability and throughput are severely limited by the mechanical probe movements, and its applicability is constrained by the low-temperature environment (usually lower than 77K) needed to stabilize the structure. Therefore, a method of controlling atoms at room temperature without mechanical movement is essential for a broader interest and unleashing the constraints.

The advancement of aberration-corrector makes it possible to focus high-energy (usually ranging from 30 keV to 300 keV) electron beams to a single-atom scale inside scanning transmission electron microscope (STEM). As well as being a versatile tool for characterizing the precise atomic structures of materials, STEM has also demonstrated the capability of controlling atoms on two-dimensional (2D) materials, like a substitutional dopant in graphene or molybdenum disulfides (MoS2). This turns the irradiation damage of electron beam (which is not what we want) to a powerful tool with a positive value (what we want). While controlling atoms using STEM is promising, it is still haunted by the fact that most of the dynamic processes are random.

A theoretical framework, called Primary Knock-on Space (PKS), will be introduced for optimizing the control process by biasing the possibilities of different atomic dynamics. This framework predicts how various external factors tunable in experiment can influence the atom dynamics. It has proved to be useful in guiding the control process towards a more deterministic route. Following the introduction, I will present two applications of the PKS framework. The future of Atomic Engineering will also be envisioned at the end.

Speaker: Cong Su, UC Berkeley

Friday, 10/11/19


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Latimer Hall

UC Berkeley
Room 120
Berkeley, CA 94720