Classical methods for achieving nucleophilic substitution reactions of alkyl electrophiles (SN1 and SN2) have limited scope and are not generally amenable to enantioconvergent variants that employ readily available racemic coupling partners. In this talk, the use of radical chemistry in combination with transition-metal catalysis to address the dual challenges of ...
Spectroscopy and microscopy have the potential to reveal the structure and dynamics of complex materials, ranging from chromophores in solution to molecular aggregates, nanomaterials, and even quantum sensors. Yet, disentangling these signals and extracting an intuitive picture of how excitations form, move, and transform is one of the most persistent ...